Article,

The Viscosity of Aqueous Alkali-Chloride Solutions up to 623 K, 1,000 bar, and High Ionic Strength

, and .
International Journal of Thermophysics, 30 (5): 1510--1523 (October 2009)
DOI: 10.1007/s10765-009-0646-7

Abstract

An accurate viscosity (dynamic viscosity) model is developed for aqueous alkali-chloride solutions of the binary systems,LiCl–H2O, NaCl–H2O, and KCl–H2O, from 273K to 623K, and from 1bar to 1,000bar and up to high ionic strength. The valid ionic strengths for the LiCl–H2O, NaCl–H2O, and KCl–H2O systems are 0 to 16.7mol · kg−1, 0 to 6mol · kg−1, and 0 to 4.5mol · kg−1, respectively. Comparison of the model with about 4,150 experimental data points concludes that the average absolute viscosity deviation from experimental data in the above range is within or about 1\% for the LiCl–H2O, NaCl–H2O, and KCl–H2O mixtures, indicating the model is of experimental accuracy. With a simple mixing rule, this model can be extrapolated to predict the viscosity of ternary aqueous alkali-chloride solutions, making it useful in reservoir fluid flow simulation. A computer code is developed for this model and can be obtained from the author: (maoshide@cugb.edu.cn).

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