%0 Journal Article %1 ISI:000258064300065 %A Sadjadi, Mirabdullah Seyed %A Ebadi, Amin %A Zare, Karim %A Amani, Vahid %A Khavasi, Hamid Reza %C COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA %D 2008 %I WILEY-BLACKWELL %J ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE %K imported %N 8 %P M1050-U725 %R 10.1107/S1600536808022320 %T mu-2,3,5,6-Tetra-2-pyridylpyrazine-kappa N-3(1),N-2,N-6 :kappa N-3(3),N-4,N-5-bis(methanol-kappa O)(nitrato-kappa O-2,O')(nitrato-kappa O)cadmium(II) %V 64 %X The title complex, Cd-2(NO3)(4)(C24H16N6)(CH4O)(2), displays a centrosymmetric dinuclear structure, in which the 2,3,5,6-tetra- 2-pyridinylpyrazine (tppz) ligand links two Cd ions separated by 7.323 (4) angstrom. Each Cd-II center is seven-coordinated by three N-atom donors of tppz in one plane, by two O atoms nearly normal to this plane, and by two O atoms 0.393 (3) and 0.488 (3) angstrom from that plane. The two Cd-II ions are above and below the plane of the pyrazine ring of the tppz ligand, oriented with respect to the pyridine rings at dihedral angles of 38.01 (3) and 31.90 (3)degrees. The dihedral angle between the two pyridine rings is 41.11 (3)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O hydrogen bonds link the molecules.

@article{ISI:000258064300065, abstract = {{The title complex, {[}Cd-2(NO3)(4)(C24H16N6)(CH4O)(2)], displays a centrosymmetric dinuclear structure, in which the 2,3,5,6-tetra- 2-pyridinylpyrazine (tppz) ligand links two Cd ions separated by 7.323 (4) angstrom. Each Cd-II center is seven-coordinated by three N-atom donors of tppz in one plane, by two O atoms nearly normal to this plane, and by two O atoms 0.393 (3) and 0.488 (3) angstrom from that plane. The two Cd-II ions are above and below the plane of the pyrazine ring of the tppz ligand, oriented with respect to the pyridine rings at dihedral angles of 38.01 (3) and 31.90 (3)degrees. The dihedral angle between the two pyridine rings is 41.11 (3)degrees. In the crystal structure, intermolecular O-H center dot center dot center dot O hydrogen bonds link the molecules.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{COMMERCE PLACE, 350 MAIN ST, MALDEN 02148, MA USA}}, affiliation = {{Sadjadi, MS (Reprint Author), Islamic Azad Univ, Dept Chem, Sci \& Res Campus, Tehran, Iran. Sadjadi, Mirabdullah Seyed; Ebadi, Amin; Khavasi, Hamid Reza, Islamic Azad Univ, Dept Chem, Tehran, Iran. Zare, Karim; Khavasi, Hamid Reza, Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran.}}, author = {Sadjadi, Mirabdullah Seyed and Ebadi, Amin and Zare, Karim and Amani, Vahid and Khavasi, Hamid Reza}, author-email = {{mirabdullahsadjadi@yahoo.com}}, biburl = {https://www.bibsonomy.org/bibtex/28033d5987d9d5d892066f3cc03ae8489/hkhavasi}, cited-references = {{BOCK H, 1992, ANGEW CHEM INT EDIT, V31, P299, DOI 10.1002/anie.199202991. Carranza J, 2004, DALTON T, P3997, DOI 10.1039/b412034p. Farrugia LJ, 1997, J APPL CRYSTALLOGR, V30, P565, DOI DOI 10.1107/S0021889897003117. Farrugia L. J., 1999, J APPL CRYSTALLOGR, V32, P837, DOI DOI 10.1107/S0021889899006020. GOODWIN HA, 1959, J AM CHEM SOC, V81, P6415, DOI 10.1021/ja01533a022. GRAF M, 1993, INORG CHIM ACTA, V204, P239, DOI 10.1016/S0020-1693(00)82931-X. Graf M, 1997, INORG CHIM ACTA, V257, P89, DOI 10.1016/S0020-1693(96)05463-1. GREAVES B, 1992, ACTA CRYSTALLOGR C, V48, P2269, DOI 10.1107/S0108270192009387. Hadadzadeh H, 2006, ACTA CRYSTALLOGR E, V62, pM2002, DOI 10.1107/S1600536806028959. LAINE P, 1995, INORG CHEM, V34, P5156, DOI 10.1021/ic00125a012. Sakai K, 2003, ACTA CRYSTALLOGR E, V59, pM411, DOI 10.1107/S1600536803011541. Sheldrick GM, 2008, ACTA CRYSTALLOGR A, V64, P112, DOI 10.1107/S0108767307043930. {*}STOE CIE, 2005, X AREA X RED X SHAPE. Yamada Y, 2000, B CHEM SOC JPN, V73, P1843, DOI 10.1246/bcsj.73.1843. Zhang L, 2005, ACTA CRYSTALLOGR E, V61, pM1760, DOI 10.1107/S1600536805024712.}}, doc-delivery-number = {{332EF}}, doi = {{10.1107/S1600536808022320}}, interhash = {d5ee611e856d80bb8eb8c0ad43a762b9}, intrahash = {8033d5987d9d5d892066f3cc03ae8489}, issn = {{1600-5368}}, journal = {{ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE}}, journal-iso = {{Acta Crystallogr. Sect. E.-Struct Rep. Online}}, keywords = {imported}, keywords-plus = {{2,3,5,6-TETRA(2-PYRIDYL)PYRAZINE TPPZ; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURE; COMPLEXES; DINUCLEAR; TETRA(2-PYRIDYL)PYRAZINE; COPPER(II)}}, language = {{English}}, month = {{AUG}}, number = {{8}}, number-of-cited-references = {{15}}, pages = {{M1050-U725}}, publisher = {{WILEY-BLACKWELL}}, research-areas = {{Crystallography}}, times-cited = {{6}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{mu-2,3,5,6-Tetra-2-pyridylpyrazine-kappa N-3(1),N-2,N-6 :kappa N-3(3),N-4,N-5-bis{[}(methanol-kappa O)(nitrato-kappa O-2,O')(nitrato-kappa O)cadmium(II)]}}, type = {{Article}}, unique-id = {{ISI:000258064300065}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{3}}, volume = {{64}}, web-of-science-categories = {{Crystallography}}, year = {{2008}} }