Article,

Decorated palladium nanoparticles on mesoporous organosilicate as an efficient catalyst for Sonogashira coupling reaction

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Journal of the Iranian Chemical Society, 18 (3): 589--601 (September 2020)
DOI: 10.1007/s13738-020-02044-4

Abstract

Reforming mesoporous silica was provided by the reaction of SBA‐15 with (3-aminopropyl)triethoxysilane, the product of which was treated with furfural to give SBA-propyl-imine-furan. In the next step, palladium chloride was attached to the functionalized SBA‐15, so Pd nanoparticles immobilized on the mentioned catalyst for providing an applicable catalyst to use in the Sonogashira cross-coupling reaction. The high stability and performance of functionalized heterogeneous hybrid catalyst of Pd@SBA-Pr-imine-furan in overall were highly essential. The nano-structured Pd@SBA-Pr-imine-furan catalyst was studied for Sonogashira cross-coupling reaction by phenylacetylene and various aryl halides under reflux conditions with a small amount of catalyst. In comparison with the earlier reports, this paper offered several benefits such as short reaction times, high yields of products, catalyst

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