%0 Journal Article %1 Archer1992 %A Archer, Donald G. %D 1992 %I NIST %J Journal of Physical and Chemical Reference Data %K 1992 aqueous thermodynamic NaCl properties equilibrium %N 4 %P 793-829 %R 10.1063/1.555915 %T Thermodynamic Properties of the NaCl+Hsub 2O System. II. Thermodynamic Properties of NaCl(aq), NaCl center-dot 2Hsub 2(cr), and Phase Equilibria %U http://link.aip.org/link/?JPR/21/793/1 %V 21 %X Equations that described the thermodynamic properties of the NaCl+H2O system were obtained from a fit to experimental results for this system. The experimental results included in the fit spanned the range of temperature of approximately 250 to 600 K and, where available, the range of pressure from the vapor pressure of the solution to 100 MPa. New equations and/or values for the following properties are given in the present work: 1) DeltafG⁰_m and DeltafH⁰_m, for formation from the elements, for NaCl(cr) for 298.15 K and 0.1 MPa, 2) DeltafG⁰_m and DeltafH⁰_m from the elements, as well as S⁰_m and C⁰_p,m, all for 298.15 K, 0.1MPa, for NaCl·2H2O(cr), 3) the change in chemical potential for both NaCl and H2O in NaCl(aq) as a function of temperature, pressure, and molality, valid from 250 to 600 K and, where available, from the vapor pressure of the solution to 100 MPa. Comparison of the accuracies of experimental methods, where possible, has also been performed.

@article{Archer1992, abstract = {Equations that described the thermodynamic properties of the NaCl+H2O system were obtained from a fit to experimental results for this system. The experimental results included in the fit spanned the range of temperature of approximately 250 to 600 K and, where available, the range of pressure from the vapor pressure of the solution to 100 MPa. New equations and/or values for the following properties are given in the present work: 1) DeltafG⁰_m and DeltafH⁰_m, for formation from the elements, for NaCl(cr) for 298.15 K and 0.1 MPa, 2) DeltafG⁰_m and DeltafH⁰_m from the elements, as well as S⁰_m and C⁰_p,m, all for 298.15 K, 0.1MPa, for NaCl·2H2O(cr), 3) the change in chemical potential for both NaCl and H2O in NaCl(aq) as a function of temperature, pressure, and molality, valid from 250 to 600 K and, where available, from the vapor pressure of the solution to 100 MPa. Comparison of the accuracies of experimental methods, where possible, has also been performed. }, added-at = {2011-01-19T18:05:20.000+0100}, author = {Archer, Donald G.}, biburl = {https://www.bibsonomy.org/bibtex/213444abb6d8acf7a108e92f5a291a40e/thorade}, description = {Thermodynamic Properties of the NaCl+H[sub 2]O System. II. Thermodynamic Properties of NaCl(aq), NaCl [center-dot] 2H[sub 2](cr), and Phase Equilibria}, doi = {10.1063/1.555915}, interhash = {dd8c97feb70635f47137579874ff8938}, intrahash = {13444abb6d8acf7a108e92f5a291a40e}, journal = {Journal of Physical and Chemical Reference Data}, keywords = {1992 aqueous thermodynamic NaCl properties equilibrium}, number = 4, pages = {793-829}, publisher = {NIST}, timestamp = {2011-01-19T18:05:20.000+0100}, title = {Thermodynamic Properties of the NaCl+H[sub 2]O System. II. Thermodynamic Properties of NaCl(aq), NaCl [center-dot] 2H[sub 2](cr), and Phase Equilibria}, url = {http://link.aip.org/link/?JPR/21/793/1}, volume = 21, year = 1992 }