Article,

Observation of Electric Quadrupole Transitions to Rydberg nd States of Ultracold Rubidium Atoms

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(Sep 13, 2008)

Abstract

We report the observation of dipole-forbidden, but quadrupole-allowed, one-photon transitions to high Rydberg states in Rb. Using pulsed UV excitation of ultracold atoms in a magneto-optical trap, we excite \$5s nd\$ transitions over a range of principal quantum numbers \$n=27-59\$. Compared to dipole-allowed (E1) transitions from \$5s np\$, these E2 transitions are weaker by a factor of approximately 2000. We also report measurements of the anomalous \$np\_3/2 : np\_1/2\$ fine-structure transition strength ratio for \$n=28-75\$. Both results are in agreement with theoretical predictions.

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