%0 Journal Article %1 ISI:000253518700022 %A Keypour, Hassan %A Azadbakht, Reza %A Khavasi, Hamidreza %C THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND %D 2008 %I PERGAMON-ELSEVIER SCIENCE LTD %J POLYHEDRON %K NMR complexes; crystal schiff-base; spectroscopy} structure; {macrocyclic %N 2 %P 648-654 %R 10.1016/j.poly.2007.10.029 %T Synthesis and characterization of three Cd(II) Schiff-base macrocyclic N3O2 complexes %V 27 %X Three polyamine ligands of N1-(2-nitrobenzyl)-N1-(2-aniinoethyl)ethane-1,2-diamine (L-1), N1-(2-nitrobenzyl)-N1-(2-aniinoethyl)propane-1,3-diamine (L-2) and N1-(2-nitrobenzyl)-N1-(3-aniinopropyl)propane-1,3-diamine (L-3) were synthesized and their cyclocondensation with 2-2-(2-formyl phenoxy)ethoxybenzaldehyde (L-4) in the presence of various metal(II) ions was examined. These reactions only in the presence of a stoichiometric amount of cadmium(II) nitrate gave the related cadmium(II) macrocyclic Schiff-base complexes. In all the other cases no cyclic complexes have been obtained and metal(II) polyamines were the only products. The complexes have been studied with IR, H-1 NMR, C-13 NMR, DEPT, COSY, HMQC and microanalysis. The crystal structures of Cd(NO3)(L-5)(mu-NO3)Cd(NO3)(L-5)0.5Cd(NO3)(4) (1) and CdL5(NO3)(CH3OH)ClO4 (2) have been also determined. (c) 2007 Elsevier Ltd. All rights reserved.

@article{ISI:000253518700022, abstract = {{Three polyamine ligands of N1-(2-nitrobenzyl)-N1-(2-aniinoethyl)ethane-1,2-diamine (L-1), N1-(2-nitrobenzyl)-N1-(2-aniinoethyl)propane-1,3-diamine (L-2) and N1-(2-nitrobenzyl)-N1-(3-aniinopropyl)propane-1,3-diamine (L-3) were synthesized and their cyclocondensation with 2-{[}2-(2-formyl phenoxy)ethoxy]benzaldehyde (L-4) in the presence of various metal(II) ions was examined. These reactions only in the presence of a stoichiometric amount of cadmium(II) nitrate gave the related cadmium(II) macrocyclic Schiff-base complexes. In all the other cases no cyclic complexes have been obtained and metal(II) polyamines were the only products. The complexes have been studied with IR, H-1 NMR, C-13 NMR, DEPT, COSY, HMQC and microanalysis. The crystal structures of {[}Cd(NO3)(L-5)(mu-NO3)Cd(NO3)(L-5)]0.5Cd(NO3)(4) (1) and {[}CdL5(NO3)(CH3OH)]ClO4 (2) have been also determined. (c) 2007 Elsevier Ltd. All rights reserved.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}}, affiliation = {{Keypour, H (Reprint Author), Bu Ali Sina Univ, Fac Chem, Hamadan, Iran. Keypour, Hassan; Azadbakht, Reza, Bu Ali Sina Univ, Fac Chem, Hamadan, Iran. Khavasi, Hamidreza, Shaheed Beheshti Univ, Dept Chem, Tehran, Iran.}}, author = {Keypour, Hassan and Azadbakht, Reza and Khavasi, Hamidreza}, author-email = {{keypour@basu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/21d30c94d36d59269fcea9f279df5c678/hkhavasi}, cited-references = {{Baillie PK, 1996, J CHEM SOC DALTON, P3039, DOI 10.1039/dt9960003039. Bradshaw J. S., 1993, AZA CROWN MACROCYCLE. Brooker S, 2001, COORDIN CHEM REV, V222, P33, DOI 10.1016/S0010-8545(01)00300-9. Busch D. H., 1996, COMPREHENSIVE SUPRAM, V9, P1. Collinson SR, 1996, COORDIN CHEM REV, V148, P19, DOI 10.1016/0010-8545(95)01156-0. FENTON DE, 1988, CHEM SOC REV, V17, P69, DOI 10.1039/cs9881700069. Fenton RR, 2002, J CHEM SOC DALTON, P2185, DOI 10.1039/b201195f. GUERRIERO P, 1995, COORDIN CHEM REV, V139, P17, DOI 10.1016/0010-8545(93)01105-7. KENNETH R, 1983, J CHEM SOC CHEM COMM, P1351. Keypour H, 1998, TRANSIT METAL CHEM, V23, P609, DOI 10.1023/A:1006988704602. Keypour H, 2000, POLYHEDRON, V19, P1633, DOI 10.1016/S0277-5387(00)00444-7. Keypour H, 2004, J IRAN CHEM SOC, V1, P53. Keypour H, 2004, TRANSIT METAL CHEM, V29, P523, DOI 10.1023/B:TMCH.0000037519.90254.03. Keypour H, 2004, INORG CHIM ACTA, V357, P1283, DOI 10.1016/j.ica.2003.10.009. Keypour H, 2003, INORG CHIM ACTA, V355, P286, DOI 10.1016/S0020-1693(03)00341-4. Keypour H, 2000, TRANSIT METAL CHEM, V25, P205, DOI 10.1023/A:1007017400893. Keypour H, 2000, INORG CHEM, V39, P5787, DOI 10.1021/ic000511m. Keypour H, 2007, INORG CHIM ACTA, V360, P2298, DOI 10.1016/j.ica.2006.11.023. OKAWA H, 1998, COORDIN CHEM REV, V174, P5175. PENG SM, 1978, INORG CHEM, V17, P119, DOI 10.1021/ic50179a025. VIGATO PA, 1990, COORDIN CHEM REV, V106, P25, DOI 10.1016/0010-8545(60)80002-1. ZANELLO P, 1987, COORDIN CHEM REV, V77, P165, DOI 10.1016/0010-8545(87)85034-8.}}, doc-delivery-number = {{267OO}}, doi = {{10.1016/j.poly.2007.10.029}}, interhash = {f676611fabd7e0ec6422639c5788dda5}, intrahash = {1d30c94d36d59269fcea9f279df5c678}, issn = {{0277-5387}}, journal = {{POLYHEDRON}}, journal-iso = {{Polyhedron}}, keywords = {NMR complexes; crystal schiff-base; spectroscopy} structure; {macrocyclic}, keywords-plus = {{2-AMINOETHYL PENDANT ARMS; ASYMMETRICAL TRIPODAL TETRAAMINES; CRYSTAL-STRUCTURE DETERMINATION; AB-INITIO; CADMIUM(II) COMPLEXES; COPPER(II); NICKEL(II); ZINC(II); LIGANDS; NMR}}, language = {{English}}, month = {{FEB 6}}, number = {{2}}, number-of-cited-references = {{22}}, pages = {{648-654}}, publisher = {{PERGAMON-ELSEVIER SCIENCE LTD}}, research-areas = {{Chemistry; Crystallography}}, times-cited = {{10}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis and characterization of three Cd(II) Schiff-base macrocyclic N3O2 complexes}}, type = {{Article}}, unique-id = {{ISI:000253518700022}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{3}}, volume = {{27}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Crystallography}}, year = {{2008}} }