A partial index is an index built over a subset of a table; the subset is defined by a conditional expression (called the predicate of the partial index). The index contains entries for only those table rows that satisfy the predicate.
CREATE INDEX access_log_client_ip_ix ON access_log (client_ip) WHERE NOT (client_ip > inet '192.168.100.0' AND client_ip < inet '192.168.100.255');